A battery is a device that converts chemical energy into electrical energy and vice versa. This summary provides an introduction to the terminology used to describe, classify, and compare batteries for hybrid, plug-in hybrid, and electric vehicles. It provides a basic background, defines the variables used to characterize battery operating conditions, and describes the manufacturer specifications used to characterize battery nominal and maximum characteristics.
Hybrid and electric vehicles have a high voltage battery pack that consists of individual modules and cells organized in series and parallel. A cell is the smallest, packaged form a battery can take and is generally on the order of one to six
volts. A module consists of several cells generally connected in either series or parallel. A battery pack is then assembled by connecting modules together, again either in series or
Not all batteries are created equal, even batteries of the same chemistry. The main trade-off in battery development is between power and energy:batteries can be either high-power or high-energy, but not both. Often manufacturers will classify batteries using these categories. Other common classifications are High Durability, meaning that the chemistry has been modified to provide higher battery life at the expense of power and energy.
In describing batteries, discharge current is often expressed as a C-rate in order to normalize against battery capacity, which is often very different between batteries. A C-rate is a measure of the rate at which a battery is discharged relative to its maximum capacity. A 1C rate means that the discharge current will discharge the entire battery in 1 hour. For a battery with a capacity of 100 Amp-hrs, this equates to a discharge current of 100 Amps. A 5C rate for this battery would be 500 Amps, and a C/2 rate would be 50 Amps. Similarly, an E-rate describes the discharge power. A 1E rate is the discharge power to discharge the entire battery in 1 hour.
Although it may not sound like it, batteries for hybrid, plug-in, and electric vehicles are all secondary batteries. A primary battery is one that can not be recharged. A secondary battery is one that is rechargeable.
This section describes some of the variables used to describe the present condition of a battery.
An expression of the present battery capacity as a
percentage of maximum capacity. SOC is generally calculated using current integration to
determine the change in battery capacity over time.
The percentage of battery capacity that has been discharged expressed as a percentage of maximum capacity. A discharge to at least 80 % DOD is referred to as a deep discharge.
The voltage between the battery terminals with load applied. Terminal voltage varies with SOC and discharge/charge current.
The voltage between the battery terminals with no load applied. The open-circuit voltage depends on the battery state of charge, increasing with state of charge.
The resistance within the battery, generally different for charging and discharging, also dependent on the battery state of charge. As internal resistance increases, the battery efficiency decreases and thermal stability is reduced as more of the charging energy is converted into heat.
Battery Technical Specifications
This section explains the specifications you may see on battery technical specification sheets used to describe battery cells, modules, and packs.
The reported or reference voltage of the battery, also sometimes thought of as the “normal” voltage of the battery.
The minimum allowable voltage. It is this voltage that generally defines the “empty” state of the battery.
The coulometric capacity, the total Amp-hours available when the battery is discharged at a certain discharge current (specified as a C-rate) from 100 percent state-of-charge to the cut-off
voltage. Capacity is calculated by multiplying the discharge current (in Amps) by the discharge time (in hours) and decreases with increasing C-rate.
The “energy capacity” of the battery, the total Watt-hours available when the battery is discharged at a certain discharge current (specified as a C-rate) from 100 percent state-of-charge to the cut-off voltage. Energy is calculated by multiplying the discharge power (in Watts) by the discharge time (in hours). Like capacity, energy decreases with increasing C-rate.
The number of discharge-charge cycles the
battery can experience before it fails to meet specific performance criteria. Cycle life is
estimated for specific charge and discharge conditions. The actual operating life of the
battery is affected by the rate and depth of cycles and by other conditions such as
temperature and humidity. The higher the DOD, the lower the cycle life.
The nominal battery energy per unit mass, sometimes referred to as the gravimetric energy density. Specific energy is a characteristic of the battery chemistry and packaging. Along with the energy consumption of the vehicle, it determines the battery weight required to achieve a given electric range.
The maximum available power per unit mass. Specific power is a characteristic of the battery chemistry and packaging. It determines the battery weight required to achieve a given performance target.
The nominal battery energy per unit volume, sometimes referred to as the volumetric energy density. Specific energy is a characteristic of the
battery chemistry and packaging. Along with the energy consumption of the vehicle, it
determines the battery size required to achieve a given electric range.
The maximum available power per unit volume. Specific power is a characteristic of the battery chemistry and packaging. It determines the battery size required to achieve a given performance target.
The maximum current at which the
battery can be discharged continuously. This limit is usually defined by the battery
manufacturer in order to prevent excessive discharge rates that would damage the battery or reduce its capacity. Along with the maximum continuous power of the motor, this defines
the top sustainable speed and acceleration of the vehicle.
The maximum current at which the
battery can be discharged for pulses of up to 30 seconds. This limit is usually defined by
the battery manufacturer in order to prevent excessive discharge rates that would damage
the battery or reduce its capacity. Along with the peak power of the electric motor, this
defines the acceleration performance (0-60 mph time) of the vehicle.
The voltage that the battery is charged to when charged to full capacity. Charging schemes generally consist of a constant current charging until the battery voltage reaching the charge voltage, then constant voltage charging, allowing the charge current to taper until it is very small.
The voltage at which the battery is maintained after being charge to 100 percent SOC to maintain that capacity by compensating for self-discharge of the battery.
The ideal current at which the battery is initially
charged (to roughly 70 percent SOC) under constant charging scheme before transitioning
into constant voltage charging.
The resistance within the battery, generally different for charging and discharging.
The above specifications are used with permission from the MIT Electric Vehicle Team:
MIT Electric Vehicle Team (2008). A guide to understanding battery specifications. http://web.mit.edu/evt/summary_battery_specifications.pdf